The modern physics of quantum mechanics was born in 1900 when Max Planck after many unsuccessful attempts in an "act of despair" introduced a universal smallest quantum of action
Planck describes this monumental moment in the history of science in his 1918 Nobel Lecture as follows:
- For many years, such an aim for me was to find the solution to the problem of the distribution of energy in the normal spectrum of radiating heat.
- Nevertheless, the result meant no more than a preparatory step towards the initial onslaught on the particular problem which now towered with all its fearsome height even steeper before me. The first attempt upon it went wrong…
- So there was nothing left for me but to tackle the problem from the opposite side, that of thermodynamics, in which field I felt, moreover, more confident.
- Since the whole problem concerned a universal law of Nature, and since at that time, as still today, I held the unshakeable opinion that the simpler the presentation of a particular law of Nature, the more general it is…
- For this reason, I busied myself, from then on, that is, from the day of its establishment, with the task of elucidating a true physical character for the formula, and this problem led me automatically to a consideration of the connection between entropy and probability, that is, Boltzmann's trend of ideas; until after some weeks of the most strenuous work of my life, light came into the darkness, and a new undreamed-of perspective opened up before me.
Planck thus finally succeeded to prove Planck's radiation law as a modification of Rayleigh-Jeans law with a high-frequency cut-off factor eliminating "the
ultraviolet catastrophe" which had paralyzed physics shortly after the
introduction of Maxwell's wave equations for electromagnetics as the
culmination of classical physics.
Planck's constant
I(ν,T)=γθ(ν,T)ν2T , whereγ=2kc2 ,
θ(ν,T)=αeα−1 ,α=hνkT ,
where ν is frequency, T temperature in Kelvin K and k=1.38×10−23J/K=8.62×10−5eV/K is Boltzmann's constant and cm/s the speed of light.
We see that θ(ν,T)≈1 for small α and enforces a high-frequency small-wavelength cut-off for α>10 , that is, for
ν>νmax≈10Th^ whereh^=hk=4.8×10−11Ks ,λ<λmin≈c10Th^ whereνλ=c ,
with maximal radiance occuring for α=2.821 in accordance with Wien's displacement law. With T=1000K the cut-off is in the visible range for ν≈2×1014 and λ≈10−6m . We see that the relation
c10Th^=λmin ,
gives h^ a physical meaning as measure of wave-length of maximal radiance and small-wavelength cut-off of atomic size scaling with cT .
We have seen that Planck's constant enters in Planck's radiation law in the form
Small-wavelength cut-off in the radiation from a body is possible to envision in wave mechanics as an expression of finite precision analog computation. In this perspective Planck's universal quantum of action emerges as unnecessary fiction about exceedingly small quantities beyond reason and reality.
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